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聚酰胺樹脂組合物及由其形成的成形品的制作方法

文(wen)檔(dang)序號:11108431閱讀:654來源:國知局

本(ben)發明(ming)涉及聚酰(xian)胺樹(shu)脂組合物及由其形成(cheng)的成(cheng)形品,特別是涉及作(zuo)為層疊體、電(dian)子部(bu)件(jian)、散熱部(bu)件(jian)或汽(qi)車(che)部(bu)件(jian)的成(cheng)形品。



背景技術:

以聚(ju)酰(xian)胺(an)6、聚(ju)酰(xian)胺(an)66為(wei)代表的聚(ju)酰(xian)胺(an)樹(shu)脂由于(yu)耐熱性(xing)(xing)(xing)、成形性(xing)(xing)(xing)優異,因此被用作電氣電子部件等的成形材料。在(zai)這些領域中,正(zheng)盛(sheng)行高性(xing)(xing)(xing)能化(hua)、小型化(hua)及輕量化(hua),使(shi)產生的熱有效地散發到外部的熱對策成為(wei)極(ji)其(qi)重要的課題。以往以來(lai),作為(wei)改良(liang)散熱性(xing)(xing)(xing)的方(fang)法,已知有在(zai)聚(ju)酰(xian)胺(an)樹(shu)脂組合物中配混導(dao)熱性(xing)(xing)(xing)填料的方(fang)法(專利文獻(xian)1及2)。

現有技術文獻

專利文獻

專(zhuan)利文獻1:日本特開(kai)平11-148007號公報

專利(li)文(wen)獻(xian)2:日本特(te)表號公報



技術實現要素:

發明要解決的問題

通過在聚酰(xian)(xian)胺(an)樹(shu)脂組合(he)物中(zhong)配(pei)混導(dao)熱(re)性(xing)(xing)(xing)填(tian)料(liao)的(de)(de)方法,為了進一步提(ti)高(gao)導(dao)熱(re)性(xing)(xing)(xing),需要在聚酰(xian)(xian)胺(an)樹(shu)脂組合(he)物中(zhong)添加(jia)大量導(dao)熱(re)性(xing)(xing)(xing)填(tian)料(liao)。但是,若大量添加(jia)導(dao)熱(re)性(xing)(xing)(xing)填(tian)料(liao),則不僅(jin)熔融粘度變高(gao)、成形性(xing)(xing)(xing)被損害(hai),還(huan)表(biao)現(xian)出耐沖(chong)擊性(xing)(xing)(xing)等機械特性(xing)(xing)(xing)也(ye)惡化的(de)(de)傾向。

本發(fa)明的目的為(wei),提供不僅具(ju)有優(you)異的機械特(te)性(xing)、還兼具(ju)良好的成形(xing)性(xing)和優(you)異的導熱性(xing)的聚酰胺樹脂組(zu)合物及由其(qi)形(xing)成的成形(xing)品(pin)。

用于解決問題的方案

本發(fa)(fa)明(ming)(ming)的發(fa)(fa)明(ming)(ming)人等為(wei)了(le)(le)解決上述問題而進行了(le)(le)深入研究(jiu),結果(guo)發(fa)(fa)現,通(tong)過(guo)將為(wei)了(le)(le)提高機械(xie)特(te)性(xing)而配混的玻璃(li)纖維和聚酰(xian)胺彈(dan)性(xing)體(ti)組(zu)合(he)而配混到聚酰(xian)胺樹(shu)脂組(zu)合(he)物(wu)中,意(yi)外的是,不僅能夠(gou)提高機械(xie)特(te)性(xing),還能夠(gou)保(bao)持(chi)良好的成形(xing)性(xing)并(bing)提高聚酰(xian)胺樹(shu)脂組(zu)合(he)物(wu)的導熱性(xing),完成了(le)(le)本發(fa)(fa)明(ming)(ming)。

本發明的主旨如下。

本(ben)發明1涉(she)及一種聚酰胺(an)樹脂(zhi)組(zu)合(he)物(wu),其包(bao)含(A)聚酰胺(an)樹脂(zhi)、(B)玻璃(li)纖維、(C)導熱性填料及(D)聚酰胺(an)彈性體,相(xiang)對于(A)、(B)、(C)及(D)的總計100質量(liang)份,(B)為9~35質量(liang)份。

本發明(ming)2涉及本發明(ming)1的聚酰胺樹脂組合物,其(qi)中,相對于(yu)(A)、(B)、(C)及(D)的總(zong)計100質量(liang)份,(D)為2~12質量(liang)份。

本發明(ming)3涉(she)及本發明(ming)1或2的聚酰胺樹脂組合物(wu),其中,相對于(A)、(B)、(C)及(D)的總計(ji)100質(zhi)量(liang)份,(C)為20~75質(zhi)量(liang)份。

本發(fa)明(ming)(ming)4涉(she)及本發(fa)明(ming)(ming)1~3中任一項的(de)(de)聚酰(xian)胺樹脂組(zu)合物,其中,(B)為選自平均纖維直(zhi)徑為6~25μm的(de)(de)玻璃纖維中的(de)(de)至(zhi)少1種。

本發明5涉及本發明1~4中(zhong)任一項的聚酰胺(an)(an)(an)樹脂組合物,其中(zhong),(A)聚酰胺(an)(an)(an)樹脂為選自由聚酰胺(an)(an)(an)6及聚酰胺(an)(an)(an)12組成的組中(zhong)的至少(shao)1種。

本發明(ming)(ming)6涉及本發明(ming)(ming)1~5中(zhong)任一項的聚(ju)酰胺樹脂組(zu)合物,其中(zhong),(C)為選自由石墨、氫氧(yang)化鎂(mei)、氧(yang)化鎂(mei)、氮(dan)化鋁、氮(dan)化硼、氮(dan)化硅(gui)及滑石組(zu)成的組(zu)中(zhong)的至(zhi)少(shao)1種(zhong)。

本發明7涉及本發明1~6中(zhong)任一項(xiang)的聚酰(xian)胺樹脂組合物(wu),其中(zhong),(D)為聚醚酰(xian)胺彈性體。

本(ben)(ben)發(fa)明8涉及本(ben)(ben)發(fa)明1~7中任(ren)一項所述(shu)的聚酰胺樹脂組合物,其中,還包含(E)多元醇。

本(ben)(ben)發明9涉及本(ben)(ben)發明8的聚酰胺樹脂(zhi)組合物,其中,(E)為季戊四醇。

本(ben)發明(ming)10涉及(ji)本(ben)發明(ming)1~7中任(ren)一項的聚酰胺樹脂組合物(wu),其僅包含(han)(A)、(B)、(C)及(ji)(D)。

本(ben)發明11涉及本(ben)發明10的(de)聚酰胺樹(shu)脂(zhi)組(zu)合物,其中,僅僅還包含(E)多元(yuan)醇。

本發(fa)(fa)明(ming)12涉(she)及本發(fa)(fa)明(ming)11的聚酰(xian)胺(an)樹(shu)脂組合物,其中,(E)為季戊四醇。

本發(fa)明(ming)(ming)13涉及本發(fa)明(ming)(ming)10~12中任一項的聚酰胺樹(shu)脂組合物(wu),其(qi)中僅僅還包含作為任意成分的添加(jia)劑。

本(ben)(ben)發明(ming)(ming)14涉及本(ben)(ben)發明(ming)(ming)13的聚(ju)酰胺樹脂組(zu)合物(wu),其中,作(zuo)為任(ren)意成分(fen)的添(tian)加劑(ji)(ji)為選自由熱穩(wen)定(ding)(ding)劑(ji)(ji)、紫(zi)外線(xian)吸收劑(ji)(ji)、光穩(wen)定(ding)(ding)劑(ji)(ji)、抗氧化(hua)劑(ji)(ji)、抗靜電劑(ji)(ji)、潤滑(hua)劑(ji)(ji)、抗粘(zhan)連劑(ji)(ji)、防霧劑(ji)(ji)、結(jie)晶成核劑(ji)(ji)、脫模劑(ji)(ji)、增塑劑(ji)(ji)、交聯劑(ji)(ji)、發泡劑(ji)(ji)及著色(se)劑(ji)(ji)組(zu)成的組(zu)中的至(zhi)少1種。

本發(fa)明15涉(she)及一種成形品,其(qi)由本發(fa)明1~14中任一項所述的聚酰(xian)胺樹(shu)脂組(zu)合物形成。

本發明16涉及本發明15的(de)成(cheng)形(xing)品,其(qi)是層疊體(ti)、電(dian)子部件(jian)、散熱部件(jian)或汽車部件(jian)。

發明的效果

通過本發明,提供(gong)不僅具(ju)有優異的機械(xie)特性(xing)、還兼具(ju)良好的成(cheng)形性(xing)和(he)優異的導熱(re)性(xing)的聚(ju)酰胺樹(shu)脂組合(he)物及由其形成(cheng)的成(cheng)形品(pin)。

具體實施方式

本發明的聚(ju)(ju)酰胺樹脂組(zu)合物包(bao)含(han)(A)聚(ju)(ju)酰胺樹脂、(B)玻璃纖維、(C)導熱性填料及(D)聚(ju)(ju)酰胺彈性體。

<(A)聚酰胺樹脂>

(A)聚(ju)(ju)酰(xian)胺(an)(an)樹脂只要是主鏈中具有(you)(you)酰(xian)胺(an)(an)鍵(-CONH-)的樹脂,就沒有(you)(you)特別限(xian)定。(A)聚(ju)(ju)酰(xian)胺(an)(an)樹脂可(ke)以以內酰(xian)胺(an)(an)、氨(an)基羧(suo)酸、二胺(an)(an)和二羧(suo)酸(尼龍鹽(yan))或二胺(an)(an)和草酸二酯為(wei)原料,通(tong)過熔融聚(ju)(ju)合(he)(he)、溶液(ye)聚(ju)(ju)合(he)(he)、固(gu)相聚(ju)(ju)合(he)(he)等(deng)公知(zhi)的方法進行聚(ju)(ju)合(he)(he)或共聚(ju)(ju)來獲(huo)得。

作為(wei)內酰(xian)(xian)胺(an),可(ke)以(yi)舉出:ε-己(ji)內酰(xian)(xian)胺(an)、ω-庚內酰(xian)(xian)胺(an)、ω-十(shi)一(yi)內酰(xian)(xian)胺(an)、ω-十(shi)二內酰(xian)(xian)胺(an)、α-吡咯(ge)烷(wan)酮、α-哌啶酮等,優選ε-己(ji)內酰(xian)(xian)胺(an)、ω-十(shi)二內酰(xian)(xian)胺(an)。

作為氨(an)(an)基(ji)羧酸(suan)(suan)(suan),可以舉(ju)出:6-氨(an)(an)基(ji)己酸(suan)(suan)(suan)、7-氨(an)(an)基(ji)庚酸(suan)(suan)(suan)、8-氨(an)(an)基(ji)辛酸(suan)(suan)(suan)、9-氨(an)(an)基(ji)壬酸(suan)(suan)(suan)、10-氨(an)(an)基(ji)癸(gui)酸(suan)(suan)(suan)、11-氨(an)(an)基(ji)十一(yi)烷酸(suan)(suan)(suan)、12-氨(an)(an)基(ji)十二烷酸(suan)(suan)(suan)等脂肪族(zu)ω-氨(an)(an)基(ji)羧酸(suan)(suan)(suan),優選6-氨(an)(an)基(ji)己酸(suan)(suan)(suan)、11-氨(an)(an)基(ji)十一(yi)烷酸(suan)(suan)(suan)、12-氨(an)(an)基(ji)十二烷酸(suan)(suan)(suan)。

作為二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an),可(ke)以舉出:乙(yi)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、三(san)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、四亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、五亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、六(liu)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、七亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、八(ba)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、九(jiu)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、十(shi)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、十(shi)一亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、十(shi)二(er)(er)(er)(er)(er)(er)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、十(shi)三(san)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、十(shi)四亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、十(shi)五亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、十(shi)六(liu)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、十(shi)七亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、十(shi)八(ba)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、十(shi)九(jiu)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、二(er)(er)(er)(er)(er)(er)十(shi)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、2-甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)-1,8-辛(xin)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、2,2,4/2,4,4-三(san)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)己(ji)(ji)(ji)烷(wan)(wan)-1,6-二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)等脂(zhi)肪(fang)族二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an);1,3-/1,4-環(huan)(huan)己(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、雙(shuang)(4-氨(an)基(ji)(ji)(ji)(ji)(ji)(ji)環(huan)(huan)己(ji)(ji)(ji)基(ji)(ji)(ji)(ji)(ji)(ji))甲(jia)(jia)(jia)烷(wan)(wan)、雙(shuang)(4-氨(an)基(ji)(ji)(ji)(ji)(ji)(ji)環(huan)(huan)己(ji)(ji)(ji)基(ji)(ji)(ji)(ji)(ji)(ji))丙烷(wan)(wan)、雙(shuang)(3-甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)-4-氨(an)基(ji)(ji)(ji)(ji)(ji)(ji)環(huan)(huan)己(ji)(ji)(ji)基(ji)(ji)(ji)(ji)(ji)(ji))甲(jia)(jia)(jia)烷(wan)(wan)、(3-甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)-4-氨(an)基(ji)(ji)(ji)(ji)(ji)(ji)環(huan)(huan)己(ji)(ji)(ji)基(ji)(ji)(ji)(ji)(ji)(ji))丙烷(wan)(wan)、1,3-/1,4-雙(shuang)(氨(an)基(ji)(ji)(ji)(ji)(ji)(ji)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji))環(huan)(huan)己(ji)(ji)(ji)烷(wan)(wan)、5-氨(an)基(ji)(ji)(ji)(ji)(ji)(ji)-2,2,4-三(san)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)-1-環(huan)(huan)戊烷(wan)(wan)甲(jia)(jia)(jia)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、5-氨(an)基(ji)(ji)(ji)(ji)(ji)(ji)-1,3,3-三(san)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)環(huan)(huan)己(ji)(ji)(ji)烷(wan)(wan)甲(jia)(jia)(jia)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、雙(shuang)(氨(an)基(ji)(ji)(ji)(ji)(ji)(ji)丙基(ji)(ji)(ji)(ji)(ji)(ji))哌(pai)嗪(qin)、雙(shuang)(氨(an)基(ji)(ji)(ji)(ji)(ji)(ji)乙(yi)基(ji)(ji)(ji)(ji)(ji)(ji))哌(pai)嗪(qin)、降冰片烷(wan)(wan)二(er)(er)(er)(er)(er)(er)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)等脂(zhi)環(huan)(huan)式二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an);間/對苯二(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)等芳香族二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)等,優選六(liu)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)、九(jiu)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)及2-甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)-1,8-辛(xin)二(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)。

作為二(er)(er)(er)(er)(er)(er)(er)(er)羧酸(suan)(suan)(suan)(suan)(suan),可以舉出:草(cao)酸(suan)(suan)(suan)(suan)(suan)、丙二(er)(er)(er)(er)(er)(er)(er)(er)酸(suan)(suan)(suan)(suan)(suan)、琥珀酸(suan)(suan)(suan)(suan)(suan)、戊二(er)(er)(er)(er)(er)(er)(er)(er)酸(suan)(suan)(suan)(suan)(suan)、己二(er)(er)(er)(er)(er)(er)(er)(er)酸(suan)(suan)(suan)(suan)(suan)、庚二(er)(er)(er)(er)(er)(er)(er)(er)酸(suan)(suan)(suan)(suan)(suan)、辛二(er)(er)(er)(er)(er)(er)(er)(er)酸(suan)(suan)(suan)(suan)(suan)、壬(ren)二(er)(er)(er)(er)(er)(er)(er)(er)酸(suan)(suan)(suan)(suan)(suan)、癸二(er)(er)(er)(er)(er)(er)(er)(er)酸(suan)(suan)(suan)(suan)(suan)、十(shi)一(yi)烷(wan)(wan)(wan)二(er)(er)(er)(er)(er)(er)(er)(er)酸(suan)(suan)(suan)(suan)(suan)、十(shi)二(er)(er)(er)(er)(er)(er)(er)(er)烷(wan)(wan)(wan)二(er)(er)(er)(er)(er)(er)(er)(er)酸(suan)(suan)(suan)(suan)(suan)、十(shi)三烷(wan)(wan)(wan)二(er)(er)(er)(er)(er)(er)(er)(er)酸(suan)(suan)(suan)(suan)(suan)、十(shi)四烷(wan)(wan)(wan)二(er)(er)(er)(er)(er)(er)(er)(er)酸(suan)(suan)(suan)(suan)(suan)、十(shi)五烷(wan)(wan)(wan)二(er)(er)(er)(er)(er)(er)(er)(er)酸(suan)(suan)(suan)(suan)(suan)、十(shi)六烷(wan)(wan)(wan)二(er)(er)(er)(er)(er)(er)(er)(er)酸(suan)(suan)(suan)(suan)(suan)、十(shi)八烷(wan)(wan)(wan)二(er)(er)(er)(er)(er)(er)(er)(er)酸(suan)(suan)(suan)(suan)(suan)、二(er)(er)(er)(er)(er)(er)(er)(er)十(shi)烷(wan)(wan)(wan)二(er)(er)(er)(er)(er)(er)(er)(er)酸(suan)(suan)(suan)(suan)(suan)等(deng)脂(zhi)肪族二(er)(er)(er)(er)(er)(er)(er)(er)羧酸(suan)(suan)(suan)(suan)(suan);1,3-/1,4-環己烷(wan)(wan)(wan)二(er)(er)(er)(er)(er)(er)(er)(er)羧酸(suan)(suan)(suan)(suan)(suan)、二(er)(er)(er)(er)(er)(er)(er)(er)環己烷(wan)(wan)(wan)甲(jia)烷(wan)(wan)(wan)-4,4’-二(er)(er)(er)(er)(er)(er)(er)(er)羧酸(suan)(suan)(suan)(suan)(suan)、降冰(bing)片烷(wan)(wan)(wan)二(er)(er)(er)(er)(er)(er)(er)(er)羧酸(suan)(suan)(suan)(suan)(suan)等(deng)脂(zhi)環式二(er)(er)(er)(er)(er)(er)(er)(er)羧酸(suan)(suan)(suan)(suan)(suan);間(jian)苯(ben)二(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)酸(suan)(suan)(suan)(suan)(suan)、對苯(ben)二(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)酸(suan)(suan)(suan)(suan)(suan)、1,4-/1,8-/2,6-/2,7-萘二(er)(er)(er)(er)(er)(er)(er)(er)羧酸(suan)(suan)(suan)(suan)(suan)等(deng)芳香族二(er)(er)(er)(er)(er)(er)(er)(er)羧酸(suan)(suan)(suan)(suan)(suan)等(deng),優選草(cao)酸(suan)(suan)(suan)(suan)(suan)及己二(er)(er)(er)(er)(er)(er)(er)(er)酸(suan)(suan)(suan)(suan)(suan)。

作為草(cao)(cao)酸(suan)(suan)(suan)二(er)(er)(er)(er)(er)酯(zhi),可以舉出:草(cao)(cao)酸(suan)(suan)(suan)二(er)(er)(er)(er)(er)甲(jia)酯(zhi)、草(cao)(cao)酸(suan)(suan)(suan)二(er)(er)(er)(er)(er)乙酯(zhi)、草(cao)(cao)酸(suan)(suan)(suan)二(er)(er)(er)(er)(er)正(zheng)(或異)丙酯(zhi)、草(cao)(cao)酸(suan)(suan)(suan)二(er)(er)(er)(er)(er)正(zheng)(或異、或叔)丁酯(zhi)等(deng)脂(zhi)肪族醇(chun)的(de)(de)草(cao)(cao)酸(suan)(suan)(suan)二(er)(er)(er)(er)(er)酯(zhi)、草(cao)(cao)酸(suan)(suan)(suan)二(er)(er)(er)(er)(er)環己酯(zhi)等(deng)脂(zhi)環式(shi)醇(chun)的(de)(de)草(cao)(cao)酸(suan)(suan)(suan)二(er)(er)(er)(er)(er)酯(zhi)及(ji)草(cao)(cao)酸(suan)(suan)(suan)二(er)(er)(er)(er)(er)苯酯(zhi)等(deng)芳香(xiang)族醇(chun)的(de)(de)草(cao)(cao)酸(suan)(suan)(suan)二(er)(er)(er)(er)(er)酯(zhi),更(geng)優選草(cao)(cao)酸(suan)(suan)(suan)二(er)(er)(er)(er)(er)正(zheng)丁酯(zhi)、草(cao)(cao)酸(suan)(suan)(suan)二(er)(er)(er)(er)(er)異丁酯(zhi)、草(cao)(cao)酸(suan)(suan)(suan)二(er)(er)(er)(er)(er)叔丁酯(zhi),進一步優選草(cao)(cao)酸(suan)(suan)(suan)二(er)(er)(er)(er)(er)正(zheng)丁酯(zhi)。

作為(A)聚酰(xian)胺(an)(an)(an)樹脂(zhi)(zhi),可以(yi)(yi)(yi)使用作為內酰(xian)胺(an)(an)(an)、氨基(ji)羧酸(suan)、二(er)胺(an)(an)(an)與(yu)二(er)羧酸(suan)(尼龍鹽)或二(er)胺(an)(an)(an)與(yu)草酸(suan)二(er)酯(zhi)的(de)聚合(he)物(wu)的(de)聚酰(xian)胺(an)(an)(an)樹脂(zhi)(zhi)、或作為它們的(de)共聚物(wu)的(de)聚酰(xian)胺(an)(an)(an)樹脂(zhi)(zhi)。(A)聚酰(xian)胺(an)(an)(an)樹脂(zhi)(zhi)可以(yi)(yi)(yi)單獨使用,也可以(yi)(yi)(yi)組合(he)使用2種(zhong)以(yi)(yi)(yi)上。

作為聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)合物,例如(ru)可以(yi)舉出:聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)己(ji)(ji)(ji)(ji)內(nei)(nei)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)6)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)十(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)一烷(wan)(wan)內(nei)(nei)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)11)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)十(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)烷(wan)(wan)內(nei)(nei)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)12)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)乙基(ji)(ji)(ji)(ji)(ji)(ji)(ji)己(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)26)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)己(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)丁二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)46)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)己(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)己(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)66)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)壬(ren)(ren)(ren)(ren)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)己(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)69)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)癸(gui)(gui)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)己(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)610)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)六(liu)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)十(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)一酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)611)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)六(liu)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)十(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)612)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)六(liu)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)對(dui)(dui)(dui)苯(ben)(ben)(ben)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)6T)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)六(liu)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)間(jian)(jian)苯(ben)(ben)(ben)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)6I)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)六(liu)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)六(liu)氫對(dui)(dui)(dui)苯(ben)(ben)(ben)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)6T(H))、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)己(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)壬(ren)(ren)(ren)(ren)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)96)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)壬(ren)(ren)(ren)(ren)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)壬(ren)(ren)(ren)(ren)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)99)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)癸(gui)(gui)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)壬(ren)(ren)(ren)(ren)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)910)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)九(jiu)(jiu)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)十(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)912)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)九(jiu)(jiu)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)對(dui)(dui)(dui)苯(ben)(ben)(ben)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)9T)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)三甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)六(liu)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)對(dui)(dui)(dui)苯(ben)(ben)(ben)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)TMHT)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)九(jiu)(jiu)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)六(liu)氫對(dui)(dui)(dui)苯(ben)(ben)(ben)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)9T(H))、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)九(jiu)(jiu)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)萘(nai)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)9N)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)十(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)己(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)106)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)壬(ren)(ren)(ren)(ren)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)癸(gui)(gui)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)109)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)十(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)癸(gui)(gui)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)1010)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)十(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)十(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)1012)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)十(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)對(dui)(dui)(dui)苯(ben)(ben)(ben)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)10T)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)十(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)六(liu)氫對(dui)(dui)(dui)苯(ben)(ben)(ben)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)10T(H))、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)十(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)萘(nai)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)10N)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)十(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)己(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)126)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)十(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)壬(ren)(ren)(ren)(ren)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)129)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)十(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)癸(gui)(gui)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)1210)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)十(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)十(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)1212)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)十(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)對(dui)(dui)(dui)苯(ben)(ben)(ben)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)12T)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)十(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)六(liu)氫對(dui)(dui)(dui)苯(ben)(ben)(ben)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)12T(H))、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)十(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)亞(ya)(ya)(ya)(ya)(ya)(ya)(ya)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)萘(nai)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)12N)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)間(jian)(jian)苯(ben)(ben)(ben)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)己(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)MXD6)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)間(jian)(jian)苯(ben)(ben)(ben)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)辛二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)MXD8)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)間(jian)(jian)苯(ben)(ben)(ben)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)壬(ren)(ren)(ren)(ren)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)MXD9)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)間(jian)(jian)苯(ben)(ben)(ben)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)癸(gui)(gui)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)MXD10)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)間(jian)(jian)苯(ben)(ben)(ben)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)十(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)MXD12)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)間(jian)(jian)苯(ben)(ben)(ben)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)對(dui)(dui)(dui)苯(ben)(ben)(ben)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)MXDT)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)間(jian)(jian)苯(ben)(ben)(ben)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)間(jian)(jian)苯(ben)(ben)(ben)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)MXDI)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)間(jian)(jian)苯(ben)(ben)(ben)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)萘(nai)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)MXDN)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)雙(4-氨(an)(an)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)環己(ji)(ji)(ji)(ji)基(ji)(ji)(ji)(ji)(ji)(ji)(ji))甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)烷(wan)(wan)十(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)PACM12)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)雙(4-氨(an)(an)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)環己(ji)(ji)(ji)(ji)基(ji)(ji)(ji)(ji)(ji)(ji)(ji))甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)烷(wan)(wan)對(dui)(dui)(dui)苯(ben)(ben)(ben)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)PACMT)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)雙(4-氨(an)(an)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)環己(ji)(ji)(ji)(ji)基(ji)(ji)(ji)(ji)(ji)(ji)(ji))甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)烷(wan)(wan)間(jian)(jian)苯(ben)(ben)(ben)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)PACMI)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)雙(3-甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)-4-氨(an)(an)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)環己(ji)(ji)(ji)(ji)基(ji)(ji)(ji)(ji)(ji)(ji)(ji))甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)烷(wan)(wan)十(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)(shi)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)PACM12)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)異(yi)氟(fu)爾酮己(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)IPD6)、聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)異(yi)氟(fu)爾酮對(dui)(dui)(dui)苯(ben)(ben)(ben)二(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)(er)甲(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)(jia)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)(an)IPDT)等。

作為共聚(ju)(ju)(ju)(ju)(ju)(ju)物(wu)(wu),例如(ru)可以舉出:己(ji)內(nei)(nei)(nei)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)/六(liu)(liu)亞(ya)甲(jia)(jia)基(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)氨(an)(an)(an)(an)基(ji)(ji)(ji)(ji)己(ji)二(er)(er)(er)(er)(er)(er)酸(suan)(suan)(suan)(suan)(suan)共聚(ju)(ju)(ju)(ju)(ju)(ju)物(wu)(wu)(聚(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)6/66)、己(ji)內(nei)(nei)(nei)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)/六(liu)(liu)亞(ya)甲(jia)(jia)基(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)氨(an)(an)(an)(an)基(ji)(ji)(ji)(ji)壬二(er)(er)(er)(er)(er)(er)酸(suan)(suan)(suan)(suan)(suan)共聚(ju)(ju)(ju)(ju)(ju)(ju)物(wu)(wu)(聚(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)6/69)、己(ji)內(nei)(nei)(nei)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)/六(liu)(liu)亞(ya)甲(jia)(jia)基(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)氨(an)(an)(an)(an)基(ji)(ji)(ji)(ji)癸二(er)(er)(er)(er)(er)(er)酸(suan)(suan)(suan)(suan)(suan)共聚(ju)(ju)(ju)(ju)(ju)(ju)物(wu)(wu)(聚(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)6/610)、己(ji)內(nei)(nei)(nei)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)/六(liu)(liu)亞(ya)甲(jia)(jia)基(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)氨(an)(an)(an)(an)基(ji)(ji)(ji)(ji)十(shi)一烷酸(suan)(suan)(suan)(suan)(suan)共聚(ju)(ju)(ju)(ju)(ju)(ju)物(wu)(wu)(聚(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)6/611)、己(ji)內(nei)(nei)(nei)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)/六(liu)(liu)亞(ya)甲(jia)(jia)基(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)氨(an)(an)(an)(an)基(ji)(ji)(ji)(ji)十(shi)二(er)(er)(er)(er)(er)(er)烷酸(suan)(suan)(suan)(suan)(suan)共聚(ju)(ju)(ju)(ju)(ju)(ju)物(wu)(wu)(聚(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)6/612)、己(ji)內(nei)(nei)(nei)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)/氨(an)(an)(an)(an)基(ji)(ji)(ji)(ji)十(shi)一烷酸(suan)(suan)(suan)(suan)(suan)共聚(ju)(ju)(ju)(ju)(ju)(ju)物(wu)(wu)(聚(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)6/11)、己(ji)內(nei)(nei)(nei)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)/月桂內(nei)(nei)(nei)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)共聚(ju)(ju)(ju)(ju)(ju)(ju)物(wu)(wu)(聚(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)6/12)、己(ji)內(nei)(nei)(nei)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)/六(liu)(liu)亞(ya)甲(jia)(jia)基(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)氨(an)(an)(an)(an)基(ji)(ji)(ji)(ji)己(ji)二(er)(er)(er)(er)(er)(er)酸(suan)(suan)(suan)(suan)(suan)/月桂內(nei)(nei)(nei)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)(聚(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)6/66/12)、己(ji)內(nei)(nei)(nei)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)/六(liu)(liu)亞(ya)甲(jia)(jia)基(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)氨(an)(an)(an)(an)基(ji)(ji)(ji)(ji)己(ji)二(er)(er)(er)(er)(er)(er)酸(suan)(suan)(suan)(suan)(suan)/六(liu)(liu)亞(ya)甲(jia)(jia)基(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)氨(an)(an)(an)(an)基(ji)(ji)(ji)(ji)癸二(er)(er)(er)(er)(er)(er)酸(suan)(suan)(suan)(suan)(suan)(聚(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)6/66/610)、己(ji)內(nei)(nei)(nei)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)/六(liu)(liu)亞(ya)甲(jia)(jia)基(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)氨(an)(an)(an)(an)基(ji)(ji)(ji)(ji)己(ji)二(er)(er)(er)(er)(er)(er)酸(suan)(suan)(suan)(suan)(suan)/六(liu)(liu)亞(ya)甲(jia)(jia)基(ji)(ji)(ji)(ji)二(er)(er)(er)(er)(er)(er)氨(an)(an)(an)(an)基(ji)(ji)(ji)(ji)十(shi)二(er)(er)(er)(er)(er)(er)烷二(er)(er)(er)(er)(er)(er)羧酸(suan)(suan)(suan)(suan)(suan)(聚(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)6/66/612)、聚(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)92/62、聚(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)102/62、聚(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)122/62、己(ji)內(nei)(nei)(nei)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)/聚(ju)(ju)(ju)(ju)(ju)(ju)異氟爾酮己(ji)二(er)(er)(er)(er)(er)(er)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)共聚(ju)(ju)(ju)(ju)(ju)(ju)物(wu)(wu)(聚(ju)(ju)(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)(xian)(xian)(xian)胺(an)(an)(an)6/IPD6共聚(ju)(ju)(ju)(ju)(ju)(ju)物(wu)(wu))等(deng)。

(A)聚(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)樹脂(zhi)優選(xuan)內酰(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)的(de)(de)聚(ju)(ju)(ju)(ju)合(he)物或基于二胺(an)(an)(an)(an)(an)(an)與(yu)二羧(suo)酸(尼龍鹽)的(de)(de)縮(suo)聚(ju)(ju)(ju)(ju)而得到的(de)(de)聚(ju)(ju)(ju)(ju)合(he)物,作為內酰(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)的(de)(de)聚(ju)(ju)(ju)(ju)合(he)物,優選(xuan)聚(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)6、聚(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)11、聚(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)12,作為基于二胺(an)(an)(an)(an)(an)(an)與(yu)二羧(suo)酸的(de)(de)縮(suo)聚(ju)(ju)(ju)(ju)而得到的(de)(de)聚(ju)(ju)(ju)(ju)合(he)物,優選(xuan)聚(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)66、聚(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)610、聚(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)612、聚(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)1010、聚(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)1012。其中,從(cong)成形加工(gong)的(de)(de)方面出發,(A)聚(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)樹脂(zhi)特(te)別優選(xuan)聚(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)6、聚(ju)(ju)(ju)(ju)酰(xian)(xian)(xian)(xian)胺(an)(an)(an)(an)(an)(an)12。

對于(A)聚酰(xian)胺樹(shu)脂,根(gen)據JIS K-6920、在(zai)96質量(liang)%的(de)硫酸(suan)中、在(zai)聚酰(xian)胺濃度1質量(liang)%、溫(wen)度25℃的(de)條件(jian)下測定的(de)相(xiang)對粘(zhan)度優選(xuan)(xuan)為(wei)1.0~6.0。若(ruo)為(wei)該范圍,則組合物的(de)熔(rong)融時的(de)粘(zhan)度適當、成形容易、能夠對得到的(de)成形品(pin)賦予良(liang)好的(de)機械特性。相(xiang)對粘(zhan)度優選(xuan)(xuan)1.5~5.0、更優選(xuan)(xuan)1.7~4.5。

(A)聚酰胺(an)樹脂可以單獨使用,也可以組(zu)合使用2種(zhong)以上。

<(B)玻璃纖維>

對(B)玻璃纖(xian)維沒有(you)特別限定,從提高玻璃纖(xian)維與(yu)聚酰胺樹(shu)脂的(de)相容(rong)性的(de)方面(mian)出發(fa),優選用上(shang)(shang)漿(jiang)劑(ji)集成束的(de)玻璃纖(xian)維。從相容(rong)性的(de)方面(mian)出發(fa),優選上(shang)(shang)漿(jiang)劑(ji)中(zhong)包(bao)含氨酯系(xi)或丙烯(xi)酸(suan)系(xi),也可以(yi)組合使(shi)用它們。

(B)玻(bo)璃(li)纖(xian)(xian)(xian)維(wei)(wei)(wei)可(ke)以使用(yong)平均纖(xian)(xian)(xian)維(wei)(wei)(wei)直(zhi)徑為6~25μm的(de)(de)玻(bo)璃(li)纖(xian)(xian)(xian)維(wei)(wei)(wei)。從由(you)組合物形成的(de)(de)成形品的(de)(de)尺寸穩定性及機(ji)械(xie)特性的(de)(de)方面出發,平均纖(xian)(xian)(xian)維(wei)(wei)(wei)直(zhi)徑優選6~23μm,例如可(ke)以使用(yong)平均纖(xian)(xian)(xian)維(wei)(wei)(wei)直(zhi)徑為10~23μm的(de)(de)玻(bo)璃(li)纖(xian)(xian)(xian)維(wei)(wei)(wei)。

(B)玻璃(li)(li)(li)纖(xian)(xian)(xian)(xian)維(wei)可以(yi)(yi)單獨(du)使用,也可以(yi)(yi)組(zu)(zu)合使用2種以(yi)(yi)上。可以(yi)(yi)使用2種以(yi)(yi)上不同的(de)(de)(de)(de)平(ping)均(jun)(jun)纖(xian)(xian)(xian)(xian)維(wei)直(zhi)徑(jing)(jing)(jing)的(de)(de)(de)(de)玻璃(li)(li)(li)纖(xian)(xian)(xian)(xian)維(wei),意外(wai)的(de)(de)(de)(de)是(shi),通(tong)過組(zu)(zu)合特定的(de)(de)(de)(de)平(ping)均(jun)(jun)纖(xian)(xian)(xian)(xian)維(wei)直(zhi)徑(jing)(jing)(jing)的(de)(de)(de)(de)玻璃(li)(li)(li)纖(xian)(xian)(xian)(xian)維(wei),導(dao)熱性會提高(gao)。作(zuo)(zuo)為(wei)(wei)玻璃(li)(li)(li)纖(xian)(xian)(xian)(xian)維(wei)的(de)(de)(de)(de)組(zu)(zu)合,例如(ru)可以(yi)(yi)舉出:(B1)平(ping)均(jun)(jun)纖(xian)(xian)(xian)(xian)維(wei)直(zhi)徑(jing)(jing)(jing)為(wei)(wei)6~11μm的(de)(de)(de)(de)玻璃(li)(li)(li)纖(xian)(xian)(xian)(xian)維(wei)與(yu)(B2)平(ping)均(jun)(jun)纖(xian)(xian)(xian)(xian)維(wei)直(zhi)徑(jing)(jing)(jing)為(wei)(wei)13~25μm的(de)(de)(de)(de)玻璃(li)(li)(li)纖(xian)(xian)(xian)(xian)維(wei)的(de)(de)(de)(de)組(zu)(zu)合。(B1)平(ping)均(jun)(jun)纖(xian)(xian)(xian)(xian)維(wei)直(zhi)徑(jing)(jing)(jing)為(wei)(wei)6~11μm的(de)(de)(de)(de)玻璃(li)(li)(li)纖(xian)(xian)(xian)(xian)維(wei)與(yu)(B2)平(ping)均(jun)(jun)纖(xian)(xian)(xian)(xian)維(wei)直(zhi)徑(jing)(jing)(jing)為(wei)(wei)13~25μm的(de)(de)(de)(de)玻璃(li)(li)(li)纖(xian)(xian)(xian)(xian)維(wei)的(de)(de)(de)(de)質量的(de)(de)(de)(de)比例((B1):(B2))可以(yi)(yi)設(she)為(wei)(wei)1:9~9:1,優(you)選5:5。作(zuo)(zuo)為(wei)(wei)(B1),優(you)選平(ping)均(jun)(jun)纖(xian)(xian)(xian)(xian)維(wei)直(zhi)徑(jing)(jing)(jing)為(wei)(wei)10~11μm的(de)(de)(de)(de)玻璃(li)(li)(li)纖(xian)(xian)(xian)(xian)維(wei),作(zuo)(zuo)為(wei)(wei)(B2),優(you)選平(ping)均(jun)(jun)纖(xian)(xian)(xian)(xian)維(wei)直(zhi)徑(jing)(jing)(jing)13~23μm的(de)(de)(de)(de)玻璃(li)(li)(li)纖(xian)(xian)(xian)(xian)維(wei)。

對(B)玻璃(li)纖(xian)維(wei)的(de)纖(xian)維(wei)長沒(mei)有特別限(xian)定,可(ke)以設為10μm~10mm,從成(cheng)形品的(de)尺寸(cun)穩(wen)定性的(de)方面出發,更優選50μm~5mm。

(B)玻璃纖(xian)維可(ke)以(yi)進行表面(mian)處(chu)理(li)(li)(li)。作(zuo)為表面(mian)處(chu)理(li)(li)(li)劑(ji),可(ke)以(yi)舉出:硅(gui)烷系(xi)化合(he)(he)物、鈦(tai)系(xi)化合(he)(he)物、鉻(ge)系(xi)化合(he)(he)物等(deng),從提高與(yu)聚酰胺樹脂的相容性的方面(mian)出發,優選(xuan)硅(gui)烷系(xi)化合(he)(he)物、鈦(tai)系(xi)化合(he)(he)物。表面(mian)處(chu)理(li)(li)(li)劑(ji)可(ke)以(yi)單(dan)獨使用,也可(ke)以(yi)組合(he)(he)使用2種以(yi)上。

作為(wei)硅(gui)(gui)烷(wan)(wan)系化合物,優(you)選(xuan)與上漿劑(ji)的(de)(de)粘接優(you)異(yi)的(de)(de)氨(an)(an)(an)(an)(an)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)硅(gui)(gui)烷(wan)(wan)系的(de)(de)偶(ou)聯(lian)劑(ji),例(li)如(ru)可以舉出:γ-氨(an)(an)(an)(an)(an)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)丙(bing)(bing)(bing)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)三(san)(san)甲(jia)(jia)(jia)(jia)(jia)氧(yang)(yang)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)硅(gui)(gui)烷(wan)(wan)、γ-氨(an)(an)(an)(an)(an)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)丙(bing)(bing)(bing)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)三(san)(san)乙(yi)(yi)氧(yang)(yang)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)硅(gui)(gui)烷(wan)(wan)、N-苯基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)-γ-氨(an)(an)(an)(an)(an)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)丙(bing)(bing)(bing)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)三(san)(san)甲(jia)(jia)(jia)(jia)(jia)氧(yang)(yang)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)硅(gui)(gui)烷(wan)(wan)、N-β-(氨(an)(an)(an)(an)(an)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)乙(yi)(yi)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji))-γ-氨(an)(an)(an)(an)(an)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)丙(bing)(bing)(bing)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)三(san)(san)甲(jia)(jia)(jia)(jia)(jia)氧(yang)(yang)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)硅(gui)(gui)烷(wan)(wan)、N-β-(氨(an)(an)(an)(an)(an)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)乙(yi)(yi)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji))-γ-氨(an)(an)(an)(an)(an)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)丙(bing)(bing)(bing)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)三(san)(san)乙(yi)(yi)氧(yang)(yang)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)硅(gui)(gui)烷(wan)(wan)、γ-氨(an)(an)(an)(an)(an)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)二硫(liu)丙(bing)(bing)(bing)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)三(san)(san)羥基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)硅(gui)(gui)烷(wan)(wan)、γ-(多亞(ya)乙(yi)(yi)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)氨(an)(an)(an)(an)(an)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji))丙(bing)(bing)(bing)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)三(san)(san)甲(jia)(jia)(jia)(jia)(jia)氧(yang)(yang)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)硅(gui)(gui)烷(wan)(wan)、N-β-(氨(an)(an)(an)(an)(an)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)乙(yi)(yi)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji))-γ-氨(an)(an)(an)(an)(an)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)丙(bing)(bing)(bing)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)甲(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)二甲(jia)(jia)(jia)(jia)(jia)氧(yang)(yang)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)硅(gui)(gui)烷(wan)(wan)、N-β-(氨(an)(an)(an)(an)(an)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)丙(bing)(bing)(bing)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji))-γ-氨(an)(an)(an)(an)(an)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)丙(bing)(bing)(bing)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)甲(jia)(jia)(jia)(jia)(jia)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)二甲(jia)(jia)(jia)(jia)(jia)氧(yang)(yang)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)硅(gui)(gui)烷(wan)(wan)、N-(三(san)(san)甲(jia)(jia)(jia)(jia)(jia)氧(yang)(yang)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)甲(jia)(jia)(jia)(jia)(jia)硅(gui)(gui)烷(wan)(wan)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)丙(bing)(bing)(bing)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji))-乙(yi)(yi)二胺、γ-二丁(ding)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)氨(an)(an)(an)(an)(an)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)丙(bing)(bing)(bing)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)三(san)(san)甲(jia)(jia)(jia)(jia)(jia)氧(yang)(yang)基(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)(ji)硅(gui)(gui)烷(wan)(wan)等。

作為鈦(tai)(tai)(tai)(tai)系化合物(wu),可以舉出:異丙(bing)基(ji)(ji)(ji)三(san)異硬脂酰基(ji)(ji)(ji)鈦(tai)(tai)(tai)(tai)酸(suan)(suan)(suan)(suan)(suan)酯(zhi)(zhi)(zhi)(zhi)、異丙(bing)基(ji)(ji)(ji)三(san)(N-氨基(ji)(ji)(ji)乙(yi)基(ji)(ji)(ji))鈦(tai)(tai)(tai)(tai)酸(suan)(suan)(suan)(suan)(suan)酯(zhi)(zhi)(zhi)(zhi)、異丙(bing)基(ji)(ji)(ji)三(san)(焦(jiao)磷(lin)(lin)(lin)酸(suan)(suan)(suan)(suan)(suan)二(er)辛酯(zhi)(zhi)(zhi)(zhi))鈦(tai)(tai)(tai)(tai)酸(suan)(suan)(suan)(suan)(suan)酯(zhi)(zhi)(zhi)(zhi)、四(si)異丙(bing)基(ji)(ji)(ji)雙(shuang)(亞(ya)磷(lin)(lin)(lin)酸(suan)(suan)(suan)(suan)(suan)二(er)辛酯(zhi)(zhi)(zhi)(zhi))鈦(tai)(tai)(tai)(tai)酸(suan)(suan)(suan)(suan)(suan)酯(zhi)(zhi)(zhi)(zhi)、鈦(tai)(tai)(tai)(tai)酸(suan)(suan)(suan)(suan)(suan)四(si)異丙(bing)酯(zhi)(zhi)(zhi)(zhi)、鈦(tai)(tai)(tai)(tai)酸(suan)(suan)(suan)(suan)(suan)四(si)丁(ding)酯(zhi)(zhi)(zhi)(zhi)、四(si)辛基(ji)(ji)(ji)雙(shuang)(二(er)(十三(san)烷基(ji)(ji)(ji))亞(ya)磷(lin)(lin)(lin)酸(suan)(suan)(suan)(suan)(suan)酯(zhi)(zhi)(zhi)(zhi))鈦(tai)(tai)(tai)(tai)酸(suan)(suan)(suan)(suan)(suan)酯(zhi)(zhi)(zhi)(zhi)、異丙(bing)基(ji)(ji)(ji)三(san)辛酰基(ji)(ji)(ji)鈦(tai)(tai)(tai)(tai)酸(suan)(suan)(suan)(suan)(suan)酯(zhi)(zhi)(zhi)(zhi)、異丙(bing)基(ji)(ji)(ji)三(san)(十二(er)烷基(ji)(ji)(ji))苯(ben)磺酰基(ji)(ji)(ji)鈦(tai)(tai)(tai)(tai)酸(suan)(suan)(suan)(suan)(suan)酯(zhi)(zhi)(zhi)(zhi)、異丙(bing)基(ji)(ji)(ji)三(san)(磷(lin)(lin)(lin)酸(suan)(suan)(suan)(suan)(suan)二(er)辛酯(zhi)(zhi)(zhi)(zhi))鈦(tai)(tai)(tai)(tai)酸(suan)(suan)(suan)(suan)(suan)酯(zhi)(zhi)(zhi)(zhi)、雙(shuang)(焦(jiao)磷(lin)(lin)(lin)酸(suan)(suan)(suan)(suan)(suan)二(er)辛酯(zhi)(zhi)(zhi)(zhi))亞(ya)乙(yi)基(ji)(ji)(ji)鈦(tai)(tai)(tai)(tai)酸(suan)(suan)(suan)(suan)(suan)酯(zhi)(zhi)(zhi)(zhi)、異丙(bing)基(ji)(ji)(ji)二(er)甲基(ji)(ji)(ji)丙(bing)烯(xi)酰基(ji)(ji)(ji)異硬脂酰基(ji)(ji)(ji)鈦(tai)(tai)(tai)(tai)酸(suan)(suan)(suan)(suan)(suan)酯(zhi)(zhi)(zhi)(zhi)、四(si)(2,2-二(er)烯(xi)丙(bing)氧基(ji)(ji)(ji)甲基(ji)(ji)(ji)-1-丁(ding)基(ji)(ji)(ji))雙(shuang)(二(er)(十三(san)烷基(ji)(ji)(ji))亞(ya)磷(lin)(lin)(lin)酸(suan)(suan)(suan)(suan)(suan)酯(zhi)(zhi)(zhi)(zhi))鈦(tai)(tai)(tai)(tai)酸(suan)(suan)(suan)(suan)(suan)酯(zhi)(zhi)(zhi)(zhi)、異丙(bing)基(ji)(ji)(ji)三(san)枯(ku)基(ji)(ji)(ji)苯(ben)基(ji)(ji)(ji)鈦(tai)(tai)(tai)(tai)酸(suan)(suan)(suan)(suan)(suan)酯(zhi)(zhi)(zhi)(zhi)、雙(shuang)(焦(jiao)磷(lin)(lin)(lin)酸(suan)(suan)(suan)(suan)(suan)二(er)辛酯(zhi)(zhi)(zhi)(zhi))氧代(dai)乙(yi)酸(suan)(suan)(suan)(suan)(suan)酯(zhi)(zhi)(zhi)(zhi)鈦(tai)(tai)(tai)(tai)酸(suan)(suan)(suan)(suan)(suan)酯(zhi)(zhi)(zhi)(zhi)、異丙(bing)基(ji)(ji)(ji)異硬脂酰基(ji)(ji)(ji)二(er)丙(bing)烯(xi)酰基(ji)(ji)(ji)鈦(tai)(tai)(tai)(tai)酸(suan)(suan)(suan)(suan)(suan)酯(zhi)(zhi)(zhi)(zhi)等。

這些之中,優選N-β-(氨(an)(an)基(ji)(ji)(ji)(ji)乙(yi)基(ji)(ji)(ji)(ji))-γ-氨(an)(an)基(ji)(ji)(ji)(ji)丙(bing)基(ji)(ji)(ji)(ji)三(san)甲(jia)(jia)(jia)氧基(ji)(ji)(ji)(ji)硅(gui)烷(wan)(wan)、N-β-(氨(an)(an)基(ji)(ji)(ji)(ji)乙(yi)基(ji)(ji)(ji)(ji))-γ-氨(an)(an)基(ji)(ji)(ji)(ji)丙(bing)基(ji)(ji)(ji)(ji)甲(jia)(jia)(jia)基(ji)(ji)(ji)(ji)二(er)甲(jia)(jia)(jia)氧基(ji)(ji)(ji)(ji)硅(gui)烷(wan)(wan)及γ-氨(an)(an)基(ji)(ji)(ji)(ji)丙(bing)基(ji)(ji)(ji)(ji)三(san)乙(yi)氧基(ji)(ji)(ji)(ji)硅(gui)烷(wan)(wan)。

<(C)導熱性填(tian)料>

對(C)導(dao)(dao)(dao)熱性(xing)(xing)填(tian)料沒有特別(bie)限定,可(ke)以(yi)(yi)舉(ju)出(chu)(chu):金(jin)屬、合金(jin)、碳(tan)系材料、氫(qing)氧(yang)(yang)(yang)(yang)化(hua)(hua)(hua)(hua)物、氧(yang)(yang)(yang)(yang)化(hua)(hua)(hua)(hua)物、氮化(hua)(hua)(hua)(hua)物等(deng)。作為(wei)(wei)金(jin)屬粉(fen)末(mo)(mo),可(ke)以(yi)(yi)舉(ju)出(chu)(chu)鋁(lv)粉(fen)末(mo)(mo)、銅粉(fen)末(mo)(mo)等(deng),作為(wei)(wei)合金(jin),可(ke)以(yi)(yi)舉(ju)出(chu)(chu)低熔點(dian)合金(jin)等(deng),作為(wei)(wei)碳(tan)系材料,可(ke)以(yi)(yi)舉(ju)出(chu)(chu)碳(tan)、石(shi)墨(mo)(mo)等(deng),作為(wei)(wei)氫(qing)氧(yang)(yang)(yang)(yang)化(hua)(hua)(hua)(hua)物,可(ke)以(yi)(yi)舉(ju)出(chu)(chu)氫(qing)氧(yang)(yang)(yang)(yang)化(hua)(hua)(hua)(hua)鋁(lv)、氫(qing)氧(yang)(yang)(yang)(yang)化(hua)(hua)(hua)(hua)鎂(mei)等(deng),作為(wei)(wei)氧(yang)(yang)(yang)(yang)化(hua)(hua)(hua)(hua)物,可(ke)以(yi)(yi)舉(ju)出(chu)(chu)氧(yang)(yang)(yang)(yang)化(hua)(hua)(hua)(hua)鋁(lv)、氧(yang)(yang)(yang)(yang)化(hua)(hua)(hua)(hua)鎂(mei)、氧(yang)(yang)(yang)(yang)化(hua)(hua)(hua)(hua)鈹、氧(yang)(yang)(yang)(yang)化(hua)(hua)(hua)(hua)鈦等(deng),作為(wei)(wei)氮化(hua)(hua)(hua)(hua)物,可(ke)以(yi)(yi)舉(ju)出(chu)(chu)氮化(hua)(hua)(hua)(hua)鋁(lv)、氮化(hua)(hua)(hua)(hua)硼、氮化(hua)(hua)(hua)(hua)硅(gui)等(deng),從導(dao)(dao)(dao)熱性(xing)(xing)的方(fang)面出(chu)(chu)發,優(you)選石(shi)墨(mo)(mo)、氫(qing)氧(yang)(yang)(yang)(yang)化(hua)(hua)(hua)(hua)鎂(mei)、氧(yang)(yang)(yang)(yang)化(hua)(hua)(hua)(hua)鎂(mei)、氮化(hua)(hua)(hua)(hua)鋁(lv)、氮化(hua)(hua)(hua)(hua)硼、氮化(hua)(hua)(hua)(hua)硅(gui)、滑石(shi)。將組合物作為(wei)(wei)導(dao)(dao)(dao)電構件使用的情況下,從導(dao)(dao)(dao)熱性(xing)(xing)及導(dao)(dao)(dao)電性(xing)(xing)的方(fang)面出(chu)(chu)發,優(you)選石(shi)墨(mo)(mo)等(deng),作為(wei)(wei)絕(jue)緣構件使用的情況下,優(you)選氧(yang)(yang)(yang)(yang)化(hua)(hua)(hua)(hua)鎂(mei)、氮化(hua)(hua)(hua)(hua)硼、滑石(shi)等(deng)。

對(dui)(dui)(C)導熱(re)性(xing)(xing)填(tian)料的形狀(zhuang)(zhuang)(zhuang)(zhuang)(zhuang)沒有(you)特(te)別(bie)限定,可(ke)以舉出:球狀(zhuang)(zhuang)(zhuang)(zhuang)(zhuang)、針狀(zhuang)(zhuang)(zhuang)(zhuang)(zhuang)、纖維(wei)狀(zhuang)(zhuang)(zhuang)(zhuang)(zhuang)、鱗(lin)片(pian)狀(zhuang)(zhuang)(zhuang)(zhuang)(zhuang)、平(ping)(ping)板狀(zhuang)(zhuang)(zhuang)(zhuang)(zhuang)、不定形狀(zhuang)(zhuang)(zhuang)(zhuang)(zhuang)等,從(cong)機械(xie)特(te)性(xing)(xing)、導熱(re)性(xing)(xing)的方(fang)面出發,優選(xuan)(xuan)鱗(lin)片(pian)狀(zhuang)(zhuang)(zhuang)(zhuang)(zhuang)、平(ping)(ping)板狀(zhuang)(zhuang)(zhuang)(zhuang)(zhuang)。對(dui)(dui)導熱(re)性(xing)(xing)填(tian)料的平(ping)(ping)均(jun)粒(li)徑(jing)沒有(you)特(te)別(bie)限制,可(ke)以設為0.1~200μm。從(cong)耐沖擊性(xing)(xing)的方(fang)面出發,平(ping)(ping)均(jun)粒(li)徑(jing)優選(xuan)(xuan)1~100μm、更優選(xuan)(xuan)5~80μm。此處,平(ping)(ping)均(jun)粒(li)徑(jing)為通過激光衍射·散射法測定的體(ti)積基準(zhun)的中值粒(li)徑(jing)。

(C)導熱性填料可(ke)以(yi)進行表面處理(li)(li),作為表面處理(li)(li)劑(ji),可(ke)以(yi)舉出硅烷系化(hua)(hua)合(he)物(wu)、鈦系化(hua)(hua)合(he)物(wu)等。可(ke)以(yi)使用作為玻璃纖維的表面處理(li)(li)劑(ji)例示出的硅烷系化(hua)(hua)合(he)物(wu)及(ji)鈦系化(hua)(hua)合(he)物(wu)。

(C)導熱性填(tian)料可以單(dan)獨使(shi)用,也可以組(zu)合使(shi)用2種(zhong)以上。

<(D)聚酰胺彈性(xing)體>

本發明(ming)的(de)(de)聚(ju)酰胺(an)樹脂組合物可(ke)以包(bao)含(D)聚(ju)酰胺(an)彈性(xing)(xing)體。通過配混(D)聚(ju)酰胺(an)彈性(xing)(xing)體,能夠實(shi)現機械(xie)特性(xing)(xing)的(de)(de)進(jin)一步改善而不損(sun)害良好的(de)(de)導熱性(xing)(xing)。

(D)聚(ju)(ju)酰胺(an)(an)彈性(xing)體(ti)優(you)選以(yi)聚(ju)(ju)酰胺(an)(an)單(dan)(dan)元為硬鏈(lian)(lian)段、以(yi)聚(ju)(ju)醚單(dan)(dan)元為軟(ruan)鏈(lian)(lian)段的聚(ju)(ju)酰胺(an)(an)彈性(xing)體(ti),例如可以(yi)舉出:通(tong)過酯鍵將硬鏈(lian)(lian)段和軟(ruan)鏈(lian)(lian)段結合而(er)成(cheng)的聚(ju)(ju)醚酯酰胺(an)(an)彈性(xing)體(ti)、通(tong)過酰胺(an)(an)鍵將硬鏈(lian)(lian)段和軟(ruan)鏈(lian)(lian)段結合而(er)成(cheng)的聚(ju)(ju)醚酰胺(an)(an)彈性(xing)體(ti)等。

硬鏈段可以由兩末端具(ju)有羧基的(de)(de)聚酰(xian)胺衍生(sheng),是包含聚酰(xian)胺形成單元和(he)選自由脂(zhi)肪族二羧酸(suan)、脂(zhi)環族二羧酸(suan)及芳香族二羧酸(suan)組成的(de)(de)組中的(de)(de)至少1種二羧酸(suan)的(de)(de)鏈段。

硬鏈(lian)段(duan)中(zhong)的(de)聚酰(xian)胺(an)形(xing)成(cheng)單(dan)元包含內酰(xian)胺(an)、氨(an)基羧酸(suan)和/或(huo)(huo)二胺(an)與(yu)二羧酸(suan)(尼龍鹽(yan)),例如可(ke)以舉出(chu)使選自由內酰(xian)胺(an)、氨(an)基羧酸(suan)、及二胺(an)與(yu)二羧酸(suan)(尼龍鹽(yan))組成(cheng)的(de)組中(zhong)的(de)1種(zhong)或(huo)(huo)2種(zhong)以上反應(ying)而得到的(de)單(dan)元。

作為(wei)內酰(xian)胺,可以舉出:ε-己內酰(xian)胺、ω-庚(geng)內酰(xian)胺、ω-十(shi)一內酰(xian)胺、ω-月桂(gui)內酰(xian)胺、2-吡咯烷酮等碳數5~20的脂(zhi)肪族(zu)內酰(xian)胺等。

作(zuo)為氨(an)基(ji)羧(suo)(suo)酸(suan)(suan),可以(yi)舉出(chu):6-氨(an)基(ji)己酸(suan)(suan)、7-氨(an)基(ji)庚(geng)酸(suan)(suan)、8-氨(an)基(ji)辛酸(suan)(suan)、10-氨(an)基(ji)癸酸(suan)(suan)、11-氨(an)基(ji)十一烷酸(suan)(suan)、12-氨(an)基(ji)十二烷酸(suan)(suan)等(deng)碳數(shu)5~20的脂肪族ω-氨(an)基(ji)羧(suo)(suo)酸(suan)(suan)等(deng)。

作(zuo)為二(er)(er)胺(an)(an)(an),可以舉出(chu):乙(yi)二(er)(er)胺(an)(an)(an)、三亞(ya)(ya)(ya)(ya)甲(jia)(jia)基(ji)(ji)(ji)(ji)二(er)(er)胺(an)(an)(an)、四亞(ya)(ya)(ya)(ya)甲(jia)(jia)基(ji)(ji)(ji)(ji)二(er)(er)胺(an)(an)(an)、六亞(ya)(ya)(ya)(ya)甲(jia)(jia)基(ji)(ji)(ji)(ji)二(er)(er)胺(an)(an)(an)、七(qi)亞(ya)(ya)(ya)(ya)甲(jia)(jia)基(ji)(ji)(ji)(ji)二(er)(er)胺(an)(an)(an)、八亞(ya)(ya)(ya)(ya)甲(jia)(jia)基(ji)(ji)(ji)(ji)二(er)(er)胺(an)(an)(an)、九(jiu)亞(ya)(ya)(ya)(ya)甲(jia)(jia)基(ji)(ji)(ji)(ji)二(er)(er)胺(an)(an)(an)、十亞(ya)(ya)(ya)(ya)甲(jia)(jia)基(ji)(ji)(ji)(ji)二(er)(er)胺(an)(an)(an)、十一亞(ya)(ya)(ya)(ya)甲(jia)(jia)基(ji)(ji)(ji)(ji)二(er)(er)胺(an)(an)(an)、十二(er)(er)亞(ya)(ya)(ya)(ya)甲(jia)(jia)基(ji)(ji)(ji)(ji)二(er)(er)胺(an)(an)(an)、2,2,4-三甲(jia)(jia)基(ji)(ji)(ji)(ji)己烷-1,6-二(er)(er)胺(an)(an)(an)、2,4,4-三甲(jia)(jia)基(ji)(ji)(ji)(ji)己烷-1,6-二(er)(er)胺(an)(an)(an)、3-甲(jia)(jia)基(ji)(ji)(ji)(ji)戊烷-1,5-二(er)(er)胺(an)(an)(an)等(deng)碳數2~20的脂肪族(zu)二(er)(er)胺(an)(an)(an)等(deng)二(er)(er)胺(an)(an)(an)化合物。

這(zhe)些之(zhi)中(zhong),從基于(yu)低(di)吸水的(de)尺寸(cun)穩(wen)定性、耐化學藥品性、機械特(te)性的(de)觀點(dian)出(chu)發(fa),優選ω-月桂內酰胺、11-氨基十一(yi)烷酸或12-氨基十二烷酸。

硬鏈段的(de)(de)二(er)(er)(er)羧(suo)酸(suan)(suan)(suan)可以(yi)作(zuo)為(wei)(wei)分子量(liang)調(diao)節(jie)劑(ji)使(shi)用。作(zuo)為(wei)(wei)二(er)(er)(er)羧(suo)酸(suan)(suan)(suan),可以(yi)舉出草(cao)酸(suan)(suan)(suan)、琥珀酸(suan)(suan)(suan)、戊二(er)(er)(er)酸(suan)(suan)(suan)、己二(er)(er)(er)酸(suan)(suan)(suan)、庚二(er)(er)(er)酸(suan)(suan)(suan)、辛二(er)(er)(er)酸(suan)(suan)(suan)、壬二(er)(er)(er)酸(suan)(suan)(suan)、癸二(er)(er)(er)酸(suan)(suan)(suan)、十(shi)二(er)(er)(er)烷二(er)(er)(er)酸(suan)(suan)(suan)那樣的(de)(de)碳數2~20的(de)(de)脂肪族二(er)(er)(er)羧(suo)酸(suan)(suan)(suan)等二(er)(er)(er)羧(suo)酸(suan)(suan)(suan)化合物。在(zai)二(er)(er)(er)羧(suo)酸(suan)(suan)(suan)的(de)(de)存在(zai)下、通過(guo)常規(gui)方法使(shi)上述聚(ju)酰(xian)胺(an)形(xing)成單元(yuan)開環聚(ju)合或縮聚(ju),由(you)此能夠得到兩末端具有羧(suo)基的(de)(de)聚(ju)酰(xian)胺(an)。

硬鏈(lian)段的數均分子量優(you)(you)選(xuan)(xuan)為300~15000,從柔軟性(xing)、成形性(xing)的觀(guan)點出(chu)發,更優(you)(you)選(xuan)(xuan)為300~6000。

軟鏈段(duan)優(you)選聚醚,例如可(ke)以(yi)(yi)舉出(chu):聚乙(yi)二醇(chun)、聚丙二醇(chun)、聚四(si)亞甲(jia)基醚二醇(chun)、下(xia)述式(1)所(suo)示的ABA型三嵌段(duan)聚醚等(deng)。它(ta)們可(ke)以(yi)(yi)單獨使用或使用2種以(yi)(yi)上。另外,可(ke)以(yi)(yi)使用通過(guo)使聚醚的末端與氨(an)等(deng)反應而得到(dao)的聚醚二胺等(deng)。軟鏈段(duan)的數均(jun)分子量優(you)選為200~6000、更優(you)選為650~2000。

(式中,x表(biao)示(shi)1~20、y表(biao)示(shi)4~50、z表(biao)示(shi)1~20。)

上(shang)述(shu)式(1)中,x及z各(ge)自獨立地優(you)選(xuan)1~18的(de)(de)整(zheng)(zheng)數(shu)(shu)(shu)(shu)、更優(you)選(xuan)1~16的(de)(de)整(zheng)(zheng)數(shu)(shu)(shu)(shu)、進一(yi)步優(you)選(xuan)1~14的(de)(de)整(zheng)(zheng)數(shu)(shu)(shu)(shu)、特別優(you)選(xuan)1~12的(de)(de)整(zheng)(zheng)數(shu)(shu)(shu)(shu)。另外,y優(you)選(xuan)5~45的(de)(de)整(zheng)(zheng)數(shu)(shu)(shu)(shu)、更優(you)選(xuan)6~40的(de)(de)整(zheng)(zheng)數(shu)(shu)(shu)(shu)、進一(yi)步優(you)選(xuan)7~35的(de)(de)整(zheng)(zheng)數(shu)(shu)(shu)(shu)、特別優(you)選(xuan)8~30的(de)(de)整(zheng)(zheng)數(shu)(shu)(shu)(shu)。

作為上述硬鏈(lian)段與(yu)上述軟鏈(lian)段的(de)組合(he)(he),可以舉出:上述舉出的(de)硬鏈(lian)段與(yu)軟鏈(lian)段的(de)各自的(de)組合(he)(he)。其中,優選月(yue)桂(gui)內酰胺的(de)開環(huan)縮(suo)聚(ju)(ju)(ju)物(wu)/聚(ju)(ju)(ju)乙二醇的(de)組合(he)(he)、月(yue)桂(gui)內酰胺的(de)開環(huan)縮(suo)聚(ju)(ju)(ju)物(wu)/聚(ju)(ju)(ju)丙二醇的(de)組合(he)(he)、月(yue)桂(gui)內酰胺的(de)開環(huan)縮(suo)聚(ju)(ju)(ju)物(wu)/聚(ju)(ju)(ju)四亞甲基(ji)醚(mi)二醇的(de)組合(he)(he)、月(yue)桂(gui)內酰胺的(de)開環(huan)縮(suo)聚(ju)(ju)(ju)物(wu)/ABA型三嵌(qian)段聚(ju)(ju)(ju)醚(mi)的(de)組合(he)(he),特別優選月(yue)桂(gui)內酰胺的(de)開環(huan)縮(suo)聚(ju)(ju)(ju)物(wu)/ABA型三嵌(qian)段聚(ju)(ju)(ju)醚(mi)的(de)組合(he)(he)。

上(shang)述(shu)硬(ying)鏈(lian)(lian)(lian)段(duan)與上(shang)述(shu)軟鏈(lian)(lian)(lian)段(duan)的(de)比(bi)例(重量比(bi))優選為(wei)硬(ying)鏈(lian)(lian)(lian)段(duan)/軟鏈(lian)(lian)(lian)段(duan)=95/5~20/80。若為(wei)該(gai)范圍,則容易(yi)(yi)避免自成形體的(de)滲(shen)出、也容易(yi)(yi)確保充(chong)分的(de)柔軟性。硬(ying)鏈(lian)(lian)(lian)段(duan)/軟鏈(lian)(lian)(lian)段(duan)(重量比(bi))更優選為(wei)90/10~30/70、特別優選為(wei)80/20~40/60。

作(zuo)為以上那樣(yang)的聚酰(xian)胺彈性(xing)體的市售品,可(ke)以舉出:Daicel-Evonik Ltd.制:Daiamide、ARKEMA公司制:Pebax、EMS-CHEMIE(Japan)Ltd.制:Grilamid、RIKEN TECHNOS CORPORATION制:HYPER ALLOY ACTYMER、Mitsubishi Engineering-Plastics Corporation制:Novamid、宇部(bu)興產株式會社制:UBESTA XPA系列等(deng)。

其中,優選“UBESTA XPA 9040X1、UBESTA XPA 9040F1、UBESTA XPA9048X1、UBESTA XPA 9048F1、UBESTA XPA 9055X1、UBESTA XPA9055F1、UBESTA XPA 9063X1、UBESTA XPA 9063F1、UBESTA XPA9068X1、UBESTA XPA 9068F1、UBESTA XPA 9040X2、UBESTA XPA9048X2、UBESTA XPA 9040F2、UBESTA XPA 9048F2”(宇部興(xing)產株式會社制)等。

(D)聚酰胺彈性體可以單獨使用,也可以組合使用2種以上。

<配(pei)混量>

本發(fa)明的(de)(de)聚(ju)(ju)(ju)酰(xian)胺樹脂(zhi)組合(he)物(wu)包含(A)聚(ju)(ju)(ju)酰(xian)胺樹脂(zhi)、(B)玻(bo)璃纖維(wei)、(C)導(dao)熱(re)性(xing)填料及(ji)(D)聚(ju)(ju)(ju)酰(xian)胺彈性(xing)體,從不(bu)僅獲得優異(yi)的(de)(de)機(ji)械(xie)特(te)性(xing),還(huan)獲得良(liang)好的(de)(de)成(cheng)形性(xing)和優異(yi)的(de)(de)導(dao)熱(re)性(xing)的(de)(de)方面出發(fa),相對于(yu)(A)、(B)、(C)及(ji)(D)的(de)(de)總(zong)計(ji)100質(zhi)(zhi)量(liang)份(fen)(fen),(B)玻(bo)璃纖維(wei)為9~35質(zhi)(zhi)量(liang)份(fen)(fen)。發(fa)現通過以該(gai)范(fan)圍將(B)配混到組合(he)物(wu)中,不(bu)僅機(ji)械(xie)特(te)性(xing)提高,還(huan)意外地在保證良(liang)好的(de)(de)成(cheng)形性(xing)的(de)(de)情況下改善了(le)導(dao)熱(re)性(xing)。由于(yu)玻(bo)璃纖維(wei)通常比聚(ju)(ju)(ju)酰(xian)胺樹脂(zhi)導(dao)熱(re)性(xing)低,因此可以說無(wu)法預測這樣的(de)(de)導(dao)熱(re)性(xing)的(de)(de)改善作用。(B)的(de)(de)量(liang)優選9~33質(zhi)(zhi)量(liang)份(fen)(fen)、更優選15~20質(zhi)(zhi)量(liang)份(fen)(fen)。

本(ben)發明(ming)的聚酰胺樹脂組(zu)合物中組(zu)合配混(B)玻(bo)璃纖(xian)維和(he)(D)聚酰胺彈性體(ti),(D)相對(dui)于(yu)(A)、(B)、(C)及(D)的總(zong)計(ji)100質(zhi)量份(fen)(fen),可以設為2~12質(zhi)量份(fen)(fen)、優選3~11質(zhi)量份(fen)(fen)、更優選4~10質(zhi)量份(fen)(fen)。

在本發明(ming)的(de)聚(ju)酰胺樹(shu)脂組合物中,(C)導熱性填料相對于(A)、(B)及(ji)(C)及(ji)(D)的(de)總計(ji)100質(zhi)(zhi)量(liang)份(fen)(fen)(fen)可以(yi)設為20~75質(zhi)(zhi)量(liang)份(fen)(fen)(fen),優(you)選(xuan)25~60質(zhi)(zhi)量(liang)份(fen)(fen)(fen)、更優(you)選(xuan)27~50質(zhi)(zhi)量(liang)份(fen)(fen)(fen)。

<(E)多元醇>

本發明的聚酰胺樹脂組(zu)合(he)物(wu)可以包含(E)多元醇(chun)。通過(E)多元醇(chun)的配混,能夠提高成形(xing)性。

對(dui)(E)多(duo)元(yuan)醇沒有特別限制,優(you)選具有150~280℃的(de)熔點(dian)。此(ci)處,熔點(dian)是指通過差(cha)示掃描(miao)量(liang)熱分析(xi)(DSC)測定時的(de)吸熱峰(熔點(dian))的(de)溫度(du)。

作為具有150~280℃的(de)熔點(dian)(dian)的(de)多元醇(chun)(chun)(chun),可以舉出:季戊四(si)醇(chun)(chun)(chun)、二季戊四(si)醇(chun)(chun)(chun)、三羥甲基乙烷(wan)等。從(cong)成形性的(de)觀點(dian)(dian)出發(fa),優(you)選季戊四(si)醇(chun)(chun)(chun)、二季戊四(si)醇(chun)(chun)(chun)。

(E)多元醇可(ke)以(yi)單(dan)獨使(shi)用(yong),也可(ke)以(yi)組合使(shi)用(yong)2種(zhong)以(yi)上。

(E)多元醇(chun)的配混(hun)量相對于(A)、(B)、(C)及(D)的總計100質(zhi)量份(fen)(fen),可以設為4質(zhi)量份(fen)(fen)以下,從成形性(xing)的方面出發,優選0.1~3質(zhi)量份(fen)(fen)、更(geng)優選0.5~1質(zhi)量份(fen)(fen)。

<任(ren)意(yi)成分>

在不損害本發明的效果的范圍內(nei),本發明的聚酰(xian)胺(an)樹(shu)脂組(zu)合物中可以配(pei)混(hun)添(tian)(tian)加(jia)(jia)劑(ji)。作為添(tian)(tian)加(jia)(jia)劑(ji),例如可以添(tian)(tian)加(jia)(jia)熱穩定劑(ji)、紫(zi)外線吸(xi)收劑(ji)、光穩定劑(ji)、抗氧(yang)化劑(ji)、抗靜(jing)電劑(ji)、潤滑劑(ji)、抗粘連(lian)劑(ji)、防霧劑(ji)、結晶成核(he)劑(ji)、脫模(mo)劑(ji)、增塑(su)劑(ji)、交聯劑(ji)、發泡劑(ji)、著色劑(ji)(顏料、染料等(deng))等(deng)。也可以使(shi)用(yong)除聚酰(xian)胺(an)彈性體以外的彈性體。

本發明的聚酰(xian)(xian)(xian)胺樹脂組合(he)物的總量(liang)(liang)(100質量(liang)(liang)%)中,為(wei)了(le)表現作為(wei)聚酰(xian)(xian)(xian)胺樹脂的特(te)性,(A)聚酰(xian)(xian)(xian)胺樹脂優(you)選為(wei)10~75質量(liang)(liang)%、更優(you)選20~70質量(liang)(liang)%、進一步優(you)選25~50質量(liang)(liang)%。

<制造方(fang)法>

對于本發明(ming)的(de)聚酰(xian)胺樹脂組合物,可以將各(ge)成(cheng)分熔(rong)融混(hun)(hun)煉來制備。對熔(rong)融混(hun)(hun)煉的(de)方法沒有特別(bie)限(xian)定,可以使(shi)用(yong)單軸擠出機(ji)(ji)、雙軸擠出機(ji)(ji)、捏合機(ji)(ji)、班伯(bo)里密煉機(ji)(ji)等混(hun)(hun)煉機(ji)(ji)進行。

<成形(xing)品>

對于本發明的(de)(de)(de)聚酰胺樹脂(zhi)組合物(wu),可以(yi)使用注射、擠出、壓制(zhi)等(deng)成形(xing)加工法來制(zhi)成成形(xing)品。由(you)本發明的(de)(de)(de)聚酰胺樹脂(zhi)組合物(wu)形(xing)成的(de)(de)(de)成形(xing)品可以(yi)用于以(yi)往的(de)(de)(de)聚酰胺樹脂(zhi)組合物(wu)的(de)(de)(de)成形(xing)品的(de)(de)(de)用途,可以(yi)以(yi)層疊體、片、薄膜等(deng)形(xing)式用于汽(qi)車構(gou)件(jian)(jian)、計算(suan)機及相關(guan)設備、光學設備構(gou)件(jian)(jian)、電氣·電子設備、信(xin)息·通(tong)信(xin)設備、精密設備、土木·建筑用品、醫療用品、家庭用品等(deng)廣泛的(de)(de)(de)用途,尤(you)其在電子部件(jian)(jian)、散(san)熱部件(jian)(jian)、汽(qi)車部件(jian)(jian)等(deng)用途中(zhong)是有用的(de)(de)(de)。

[實施例]

以下,舉(ju)出實施例及比較例對本發明(ming)進行說(shuo)明(ming),但本發明(ming)不(bu)限定于以下的例子。

以(yi)下(xia)示(shi)出各種(zhong)評價方法和使(shi)用(yong)的原材料。

(使用原料)

(A)聚酰胺樹脂

(A-1):聚酰胺6(宇部興產株式會社制P1011F、通過了(le)10目的篩網(wang)的粉(fen)末、相對(dui)粘度2.22)

(B)玻璃纖維

(B-1):上(shang)漿劑為氨(an)酯系的(de)、平均纖(xian)維(wei)(wei)直徑10.0μm、纖(xian)維(wei)(wei)長3mm的(de)玻璃纖(xian)維(wei)(wei)

(B-2):上漿劑為(wei)氨酯系的、平均纖(xian)維(wei)直徑10.5μm、纖(xian)維(wei)長3mm的玻璃纖(xian)維(wei)

(B-3):上(shang)漿劑(ji)為氨(an)酯系的、平(ping)均纖維(wei)直徑(jing)13μm、纖維(wei)長3mm的玻璃(li)纖維(wei)

(B-4):上漿劑為(wei)氨酯系的、平均纖(xian)維直徑(jing)17μm、纖(xian)維長3mm的玻璃纖(xian)維

(B-5):上(shang)漿(jiang)劑(ji)為(wei)氨酯(zhi)系的、平均纖維直徑(jing)23μm、纖維長3mm的玻璃(li)纖維

(B-6):以質量比5:5組合使用上(shang)漿劑為氨(an)酯系的、平(ping)(ping)均(jun)纖(xian)(xian)維(wei)直徑(jing)10.5μm、纖(xian)(xian)維(wei)長(chang)(chang)3mm的玻璃纖(xian)(xian)維(wei)和上(shang)漿劑為氨(an)酯系的、平(ping)(ping)均(jun)纖(xian)(xian)維(wei)直徑(jing)17μm、纖(xian)(xian)維(wei)長(chang)(chang)3mm的玻璃纖(xian)(xian)維(wei)。

(C)導熱性填料

(C-1):石墨(mo)、鱗片狀、平均粒徑33μm

(C-2):氧化鎂、球狀(zhuang)、平(ping)均粒徑37μm

(C-3):氮化(hua)硼、板狀、平均粒徑38μm

(D)聚酰胺彈性體

(D-1):聚醚酰胺彈性(xing)體(ti)(宇部興產(chan)株式(shi)會社制(zhi)UBESTA XPA P9040X1、將顆粒粉碎并通過了10目(mu)的篩(shai)網的粉末)

(D’)其他(ta)橡膠成分

(D’-1):馬來酸(suan)改性乙烯-丁烯樹脂(三(san)井(jing)化學株式會社(she)制TAFMER MH5020)

(D’-2):離聚(ju)物(Dupont-Mitsui Polychemicals Co.,Ltd.制Himilan1855)

(D’-3):氫(qing)化苯乙烯系(xi)熱塑(su)性(xing)彈性(xing)體(旭化成化學株式會社(she)制Tuftec M1913)

(E)多元醇

(E-1):季戊四醇(chun)(日本合成化(hua)學工業株式會社(she)制(zhi)、熔點260℃、比重1.4)

按表1中示出的(de)配方(表示為質量份),將各成(cheng)分投入(ru)到(dao)圓筒(tong)型混(hun)(hun)合機中進(jin)行混(hun)(hun)合。將該混(hun)(hun)合物(wu)導入(ru)到(dao)日本制鋼株式(shi)會社制混(hun)(hun)煉機TEX44中,在設(she)定溫度280℃、螺桿轉(zhuan)速200rpm、噴(pen)出量30kg/hr下進(jin)行熔融混(hun)(hun)煉,擠出為繩狀,在水(shui)槽中冷卻后,使用造粒機,得到(dao)實施例·比較例的(de)聚(ju)酰胺(an)樹(shu)脂組合物(wu)的(de)顆粒。

(評價方法)

(1)混煉性

如下對實施例·比(bi)較例的顆粒制造中的混煉性進(jin)行判定。

×:從(cong)模(mo)具到造粒機,線料(liao)不斷開,無法進(jin)行顆粒化

○:從模具到造粒(li)機(ji),線(xian)料(liao)不斷開,能(neng)夠進行顆粒(li)化(hua)

(2)流動性

使用實施例·比較例的(de)顆(ke)粒,在料筒溫度280℃、模(mo)具溫度80℃、注射壓力100Mpa的(de)條件下(xia),進行(xing)流(liu)動(dong)長度測定。

(3)導熱性

使用實(shi)施例(li)·比較例(li)的顆粒,在(zai)料筒溫度280℃、模具溫度80℃下(xia)成形長度200、寬度40、厚度5mm的試(shi)驗(yan)片(pian)(pian)。對3張試(shi)驗(yan)片(pian)(pian),在(zai)各試(shi)驗(yan)片(pian)(pian)間(jian)均勻地涂布導(dao)熱性(xing)糊劑(2.4W/(m·K))5g,將(jiang)3張重疊(die)。通過(guo)探針法測定導(dao)熱率。

(4)耐沖擊性

根據(ju)ISO179-1/1eA,在23℃下進行(xing)測定。

[表1-1]

[表1-2]

可(ke)知(zhi)實(shi)施(shi)例(li)(li)(li)具有良好的(de)(de)(de)(de)生產率(lv),能夠在不(bu)損害成形(xing)性(xing)的(de)(de)(de)(de)情況(kuang)下(xia)提高導熱率(lv)、提高耐沖擊性(xing)。通(tong)過實(shi)施(shi)例(li)(li)(li)1與比(bi)(bi)(bi)較例(li)(li)(li)2、3的(de)(de)(de)(de)對(dui)比(bi)(bi)(bi)、實(shi)施(shi)例(li)(li)(li)2與比(bi)(bi)(bi)較例(li)(li)(li)2、4的(de)(de)(de)(de)對(dui)比(bi)(bi)(bi),可(ke)知(zhi)這些效(xiao)(xiao)果(guo)是由在聚(ju)(ju)(ju)酰(xian)胺(an)(an)彈性(xing)體(ti)的(de)(de)(de)(de)基(ji)礎上(shang)進而將(jiang)特定量的(de)(de)(de)(de)玻(bo)(bo)(bo)璃(li)纖維(wei)(wei)(wei)配混(hun)到(dao)聚(ju)(ju)(ju)酰(xian)胺(an)(an)樹脂(zhi)(zhi)組合物中(zhong)帶來的(de)(de)(de)(de)。在使(shi)用了除聚(ju)(ju)(ju)酰(xian)胺(an)(an)彈性(xing)體(ti)以(yi)外的(de)(de)(de)(de)橡膠成分的(de)(de)(de)(de)比(bi)(bi)(bi)較例(li)(li)(li)5~7中(zhong)得不(bu)到(dao)這樣的(de)(de)(de)(de)效(xiao)(xiao)果(guo)。另外,通(tong)過實(shi)施(shi)例(li)(li)(li)1~10與比(bi)(bi)(bi)較例(li)(li)(li)1~4、8及(ji)(ji)9的(de)(de)(de)(de)對(dui)比(bi)(bi)(bi),可(ke)知(zhi)在缺少聚(ju)(ju)(ju)酰(xian)胺(an)(an)樹脂(zhi)(zhi)、玻(bo)(bo)(bo)璃(li)纖維(wei)(wei)(wei)、導熱性(xing)填料及(ji)(ji)聚(ju)(ju)(ju)酰(xian)胺(an)(an)彈性(xing)體(ti)之(zhi)中(zhong)的(de)(de)(de)(de)至少一個的(de)(de)(de)(de)聚(ju)(ju)(ju)酰(xian)胺(an)(an)樹脂(zhi)(zhi)組合物的(de)(de)(de)(de)情況(kuang)下(xia),得不(bu)到(dao)本(ben)發(fa)明(ming)的(de)(de)(de)(de)期望(wang)(wang)的(de)(de)(de)(de)效(xiao)(xiao)果(guo)。進而,通(tong)過實(shi)施(shi)例(li)(li)(li)1~10與比(bi)(bi)(bi)較例(li)(li)(li)10及(ji)(ji)11的(de)(de)(de)(de)對(dui)比(bi)(bi)(bi)可(ke)知(zhi),在即使(shi)包含聚(ju)(ju)(ju)酰(xian)胺(an)(an)樹脂(zhi)(zhi)、玻(bo)(bo)(bo)璃(li)纖維(wei)(wei)(wei)、導熱性(xing)填料及(ji)(ji)聚(ju)(ju)(ju)酰(xian)胺(an)(an)彈性(xing)體(ti),但不(bu)以(yi)規定范圍的(de)(de)(de)(de)量包含玻(bo)(bo)(bo)璃(li)纖維(wei)(wei)(wei)的(de)(de)(de)(de)聚(ju)(ju)(ju)酰(xian)胺(an)(an)樹脂(zhi)(zhi)組合物的(de)(de)(de)(de)情況(kuang)下(xia),也得不(bu)到(dao)本(ben)發(fa)明(ming)的(de)(de)(de)(de)期望(wang)(wang)的(de)(de)(de)(de)效(xiao)(xiao)果(guo)。

產業上的可利用性

根(gen)據本(ben)發明,提供了不僅(jin)具有優異的(de)機械特(te)性、還(huan)兼具良好的(de)成(cheng)(cheng)(cheng)形(xing)性和優異的(de)導熱性的(de)聚酰(xian)胺樹脂(zhi)組合物(wu)(wu)及由其形(xing)成(cheng)(cheng)(cheng)的(de)成(cheng)(cheng)(cheng)形(xing)品。由本(ben)發明的(de)聚酰(xian)胺樹脂(zhi)組合物(wu)(wu)形(xing)成(cheng)(cheng)(cheng)的(de)成(cheng)(cheng)(cheng)形(xing)品可以(yi)用(yong)(yong)(yong)于以(yi)往聚酰(xian)胺樹脂(zhi)組合物(wu)(wu)的(de)成(cheng)(cheng)(cheng)形(xing)品的(de)用(yong)(yong)(yong)途,可以(yi)以(yi)層疊(die)體、片、薄膜等(deng)形(xing)式用(yong)(yong)(yong)于汽車構(gou)件、計算機及相關設備(bei)(bei)、光學設備(bei)(bei)構(gou)件、電(dian)氣·電(dian)子設備(bei)(bei)、信息·通信設備(bei)(bei)、精密設備(bei)(bei)、土木·建筑用(yong)(yong)(yong)品、醫療用(yong)(yong)(yong)品、家庭(ting)用(yong)(yong)(yong)品等(deng)廣泛的(de)用(yong)(yong)(yong)途,尤(you)其是在電(dian)子部(bu)(bu)件、散(san)熱部(bu)(bu)件、汽車部(bu)(bu)件等(deng)用(yong)(yong)(yong)途中是有用(yong)(yong)(yong)的(de)。

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